Mid-gap trap state-mediated dark current in organic photodiodes

نویسندگان

چکیده

Abstract Photodiodes are ubiquitous in industry and consumer electronics. Constantly emerging new applications for photodiodes demand different mechanical optoelectronic properties from those provided by conventional inorganic-based semiconductor devices. This has stimulated considerable interest the use of organic semiconductors, which provide a vast palette available properties, can be incorporated into flexible form factor geometries, promise low-cost, low-embodied energy manufacturing earth-abundant materials. The sensitivity photodiode depends critically on dark current. Organic (OPDs), however, characterized much higher current than expected thermally excited radiative transitions. Here we show that saturation OPDs is fundamentally limited mid-gap trap states. insight generated universal trend observed large set further substantiated sensitive external-quantum-efficiency- temperature-dependent measurements. Based this insight, an upper limit specific detectivity established. A detailed understanding origins noise any detector fundamental to defining performance limitations thus critical materials device selection, design optimization all applications. Our work establishes these important principles OPDs.

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ژورنال

عنوان ژورنال: Nature Photonics

سال: 2023

ISSN: ['1749-4885', '1749-4893']

DOI: https://doi.org/10.1038/s41566-023-01173-5